Sensitization was evaluated by double loop electrochemical potentiokinetic reactivation method and igscc studies were carried out using slow strain rate tests in polythionic acid pta. The stress corrosion cracking sco of sensitized type 304 stainless steel. What are the industrial practices being followed in. Effect of polythionic acid concentration on stress corrosion. It has general corrosion resistance similar to the low carbon 304 304l. Type 321 is a good choice for service in the stress relieved condition in environments which might otherwise cause intergranular corrosion for unstabilized alloys. Ahmad 1 oil and natural gas commission, eastern region, sibsagar785640, assam, india. Polythionic acid stress corrosion cracking pascc occurs in refinery units processing sulfurous streams. The resistances of aisi 308 and 309 weld metals to polythionic acid intergranular stress corrosion cracking were discussed regarding their use in direct desulfurizing reactors. Corrosion is not caused by the amine itself, but results from dissolved acid. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Transgranular stress corrosion cracking in type 304 austenitic stainless.
Stress corrosion cracking behavior of cold worked and. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Alloy 347347h heat resistant stainless steel plate. Stressed sensitized 304, 316, and 321 stainless steels were selected and subjected to various environments that. Type 321ss gave better resistance to scc than 304 and 316 ss in the three. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Alloy 321 resists polythionic acid stress corrosion cracking in hydrocarbon service. The types 321, 347 and 348 alloys are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steels, such as type 304. Polythionic stress corrosion cracking of stainless steel tube environment. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Type 321 is a good choice for service in the stressrelieved condition in environments which might otherwise cause intergranular corrosion for unstabilized alloys. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Pdf stress corrosion cracking of sensitized austenitic.
Stress corrosion cracking behavior of cold worked and sensitized type 304 stainless steel using the slow strain rate test. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in. How to weld repair 304h flange that has scc due to.
Exposure of nonstabilized austenitic stainless steel to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. Stresscorrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. Polythionic acid cracking is a type of intergranular corrosion affecting sensitized stainless steels in refineries processing sulfur containing feedstocks. Investigations were made to see the effect of mild to severe deformations ranging from 0 to 80% reduction in thickness on lowtemperature sensitization. Intergranular cracking tendencies of fourteen stainless steels and two highnickel alloys have been evaluated by exposing numerous specimens to polythionic acid and standard acid copper sulfate solutions. Often in many product forms, the grain size and carbon content can meet both the 347s and 347h requirements. Pascc of 304 stainless steel charge heater tubes occurred in a naphtha hydrotreater during shutdown, after about 18 years in service. The test solution was prepared by passing sulfur dioxide gas into deionized water for 4 hours and then bubbling hydrogen sulfide for 3 hours. Polythionic acid stresscorrosion cracking pascc occurs in refinery units processing sulfurous streams. Polythionic acid stress corrosion cracking pascc occurs in. Experience with polythionic acid stress corrosion cracking in.
Ambient temperature stresscorrosion cracking of sensitized stainless steels. On the mechanism of intergranular stress corrosion. The alloy can be utilized in most diluted organic acids at moderate temperatures and in pure phosphoric acid at lower temperatures and up to 10% diluted solutions at high temperatures. Stresscorrosion cracking of sensitized type 304 stainless. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Pdf stress corrosion cracking of sensitized austenitic stainless. Effect of polythionic acid concentration on stress. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Stress corrosion cracking susceptibility of stainless steels.
I have a large diameter ss304h flange that has several cracks in the process exposed face. However, in some instances, stabilized austenitic sss have been found to be susceptible to pitting, crevice. Why does chloride stress corrosion cracking and pascc only. Alloy 321 stainless steel plate does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid service.
Polythionic acid stress corrosion cracking deterioration. Pdf polythionic acid corrosion in refinery hydroprocessors. Cracking seems to have developed after shutdown and exposure to atmosphere. Type 321 is particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steels such as type 304. The commonly used types of stainless steels, 304304h and 316316h are. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Stress corrosion cracking issues in syngas plants that may be. All of the cracks observed were found underneath the coke deposits. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx.
Polythionic stress corrosion cracking of stainless steel tube. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304. Failure of 321 stainless steel heater tube in heavy crude oil. Sensitization and intergranular stress corrosion cracking igscc behavior of deformed aisi 304 prior to aging at temperature 500 c were investigated. Influence of cold rolling on sensitization and intergranular. Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. Examples of polythionic acid scc pascc in a sensitized austenitic stainless steel and caustic scc in carbon steel equipment are presented. Resistant to chloride and polythionic acid stress corrosion cracking. Polythionic acid stress corrosion cracking pascc is an affliction of many. It can also be used in chloride or fluoridefree caustic. Ctlpolythionic stress corrosion cracking of stainless.
Results reveal that the stress corrosion life decreases rapidly on increasing the concentration from 0. The applications for stainless steels in petroleum refining are many and varied. Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steels, such as alloy 304. In this chapter, the conditions for the occurrence of scc are first introduced. The temperature of the column in the region of the cracking is approximately 70c 158f. Mar 23, 2010 the purpose of this paper is to investigate stress corrosion cracking scc for 304, 316, and 321 stainless steels in petroleum. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. The cracks are intergranular and narrow with no significant branching. However, it is subject to carbide precipitation in the heat affected zone haz of welds. During the scc test, the steel specimen was subjected to threepoint bending with constant strain at room temperature, and. A hydrotest at 735 psi revealed numerous leaks in four tubes from a heater. Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r.
To add this web app to the home screen open the browser option menu and tap on add to homescreen. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Has anyone developed a recommended cleaning, excavation and weld repair procedure. An electrochemical study on stress corrosion cracking of. It can also be utilized in chloride or fluoride free caustic solutions at moderate temperatures. Stress corrosion cracking issues in syngas plants that may. Both 347 and 321 offer good resistance to polythionic acid stress corrosion cracking, encountered in oil refineries. Amine corrosion refers to the general andor localized corrosion that occurs principally on carbon steel in amine treating processes. Results show that alloys 304 and 304l, in the solution. The cracking was found when rust stainingleaks were observed. An austenitic stainless steel for sulfuric acid corrosion environments. Polythionic acid stress corrosion cracking in heater pipes. Stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0.
This paper reports the observed susceptibility of type 304 austenitic stainless steel to stress corrosion cracking in the corrosive media and its high resistance to uniform corrosion of below 0. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Alloy 347 stainless steel plate does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid. The importance of a conjoint action of corrosion and stress as well as the nature of. Ambient temperature stress corrosion cracking of sensitized stainless steels. Effects of fluoride and other halogen ions on the external. They have high strength, excellent fabrication characteristics, and can readily meet a wide range of design demands load, service life, low maintenance, etc.
Electrochemical studies of stress corrosion cracking of. Experience with polythionic acid stress corrosion cracking in reactor 0707 petroleum 14 feb 07 10. Weldments may be sensitive to haz intergranular corrosion in oxidizing acid environments, and to polythionic acid stress corrosion cracking. Ambient temperature stresscorrosion cracking of sensitized. Electrochemical studies of stress corrosion cracking of sensitized aisi 304 stainless steel in polythionic acids s. Electrochemical characteristics of polythionic acid stress corrosion cracking have been examined mainly on sensitized type 304 stainless steel. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Type 304l shares disadvantages of 304h it does sensitize at high temperature, however and can be susceptible to polythionic acid stress corrosion cracking during shut down, especially if the regenerator is water washed. It is a very severe, rapid form of intergranular scc that attacks sensitized austenitic stainless steels such a weld hazs in type 304.
In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. These acids form during downtime turnarounds after air enters the. In the presence of sulfide corrosion products, such conditions are met during shutdown, when moisture originates from general humidity, washing or steam out and oxygen as air enters the unit upon opening to atmosphere. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Stabilized austenitic stainless steels sss have since been widely used in the petroleum refining industry because of their resistance to sulphidic corrosion and polythionic acid stress corrosion cracking scc, as well as of their excellent strength and toughness. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Stress corrosion cracking of sensitized austenitic stainless. The stress corrosion cracking scc of a commercial austenitic stainless steel type 316 was investigated as a function of sensitizing temperature 7500 k and test temperature 333373 k.
Alloy 321 does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid service. Pascc of 304 stainless steel charge heater tubes occurred in a. Stress corrosion cracking of sensitized austenitic. Sem fractograph of intergranular scc of type 316 stainless steel in polythionic acid showing brittle features. The purpose of this paper is to investigate stress corrosion cracking scc for 304, 316, and 321 stainless steels in petroleum. Overview of polythionic acid stress corrosion cracking pascc.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Cracking investigation of a pressure transmitter tapping line. Examples of polythionic acid scc pascc in a sensitized austenitic. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting. The sensitization curves for solutionannealed wrought stainless steels, which had been held for varying times at temperatures. The high temperature oxidation resistance of 347 is similar to that of 304 stainless steel. Alloy 347 stainless steel plate resists polythionic acid stress corrosion cracking in hydrocarbon service. Intergranular stress corrosion cracking scc mechanism in sensitized stainless steel type 304 was investigated experimentally. A tetrathionic potassium k 2 s 4 o 6 chemical solution was used to mimic polythionic acid scc which the most aggressive scc type. Stress corrosion cracking susceptibility of stainless. Two examples of stress corrosion cracking scc in refinery equipment are presented to highlight the lessons learned to prevent recurrence of such failures. Polythionic acid is a generic term used to describe acids of the form h 2 s x o 6. Stainless steel 321 tubes opposes polythionic acid stress corrosion cracking in hydrocarbon service.
Cracking of sensitized stainless steels inspectioneering. Corrosion behavior of austenitic stainless steel in. Jan 27, 2020 the alloy can be utilized in most diluted organic acids at moderate temperatures and in pure phosphoric acid at lower temperatures and up to 10% diluted solutions at high temperatures. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Alloy for resistance to polythionic acid stress corrosion cracking for. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Experience with polythionic acid stress corrosion cracking.
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